Jyoti Juyal* and Sanjay K Sharma
Department of Chemistry, JECRC University, Jaipur (Raj.)
Correspondence author: Jyoti Juyal
Mail id of correspondence author: juyaljyotibiochem@gmail.com
Abstract
Vibrant color clothes add flavor and confidence to our attire and imparts attraction to the fabric but the use of color for dying has become a big environmental hazard. Wastewater generated from the textile industries containing dye is a major source of environmental pollution. Several materials of organic and inorganic origin have been reported for degradation of such pollutants i.e dye. Chitin, a polysaccharide of animal origin, is obtained from waste material of seafood industries. It occurs in the skeletal material of crustaceans such as crabs, lobsters, shrimps, prawns and crayfish. It is extracted as a pure polysaccharide. Further deacetylation produces chitosan. The chitosan is most significant and is commonly having different applications. The present study provides a deep insight dealing with the preparation of cost effective organic chitosan nanoparticles and their effect on particular dye degradation namely Reactive red 158 and Reactive blue 5 dyes. Chitosin nanoparticles concentration of 1 g/L, removal efficiency rates at pH 4, 9, and 7 has been assessed, and optimum pH was achieved. The effect of contact time (10, 30, 60, 90, and 120 minutes) and concentration of the nanoparticles with each of the respective dyes (50 mg/L) was investigated. The percentage of color removal has been further calculated. The results obtained indicate that after increasing the nanoparticles concentration in the solution, the concentration of hy¬droxyl radicals that play the main role in decompo¬sition of dye and other contaminants were increased, which provided a clear and gradual increase in degradation of Reactive red 158 and Reactive blue 5 dyes and their color removal.
Keywords:
:
Chitosan, De-proteinization, Demineralization, nanoparticles, dye degradation, color removal, ultrasound irradiation.
References
References:
1. Ahmad, A., Mubarak, N., Naseem, K., & Tabassum, H. (2020). Recent advancement and development of chitin and chitosan-based nanocomposite for drug delivery: Critical approach to clinical research. Arabian Journal of Chemistry , 8935-8964.
2. B, G. K., & N, S. (1993). Use of proteolytic enzymes to facilitate the recovery of chitin from shrimp wastes. Food Biotechnol, 253-262.
3. Calvo P, R.-L. C.-J. (1997). Novel hydrophilic chitosan-polyethylene oxide nanoparticles as protein carriers. Journal of Applied Polymer Science , 125-132.
4. Debnath, K. S. (2018). Development and evaluation of Chitosan nanoparticles based dry powder inhalation formulations of Prothionamide. PLoS One , 218-230.
5. Elieh-Ali-Komi, D., & Hamblin, R. M. (2017). Chitin and Chitosan: Production and Application of Versatile Biomedical Nanomaterials. International Journal of Advance Research , 411-427.
6. Gerhard, K., Jürgen, K., & Jon, V. G. (2010). Biodiesel Production. The Biodiesel Handbook (Second Edition) , 67-96.
7. Ghaderpoori M, G. S. (2016). Removal of blue cat 41 dye from aqueous solutions with ZnO nanoparticles in combination with US and US-H2O2 advanced oxidation processes. Environmental Health Engineering and Management Journal, 107-113.
8. Helin, W. F. (2000). Degradation mechanism of azo dye C. I. reactive red 2 by iron powder reduction and photooxidation in aqueous solutions. Chemosphere, 1233-1238.
9. Jolles, P., & Muzzarelli, R. A. (1999). Chitin and Chitinase. Boston: Birkhauser Verlag.
10. Li JT, L. R. (2013). Ultrasonic degradation of Fuschin in basic aqueous solution : Effects of of perating parameters and additives. International Journal of Photo Energy, 01-07.
11. López-Fernández, O., Domínguez, R., Pateiro, M., & Rocchetti, G. (2020). Determination of Polyphenols Using Liquid Chromatography–Tandem Mass Spectrometry Technique (LC–MS/MS): A Review. Antioxidants (Basel) , 479-490.
12. LoïcCrouzier, A. S. (2019). A new method for measuring nanoparticle diameter from a set of SEM images using a remarkable point. Ultramicroscopy, 112847.
13. Mathur A, R. A. (2011). Isolation of Bacillus producing chitinase from soil: Production and purification of chito-oligosaccharides from chitin extracted from fresh water crustaceans and antimicrobial activity of chitinase. The Recent Research in Science and Technology, 01-06.
14. Mótyán, A. J., Tóth, F., & Tőzsér, J. (2013). Research Applications of Proteolytic Enzymes in Molecular Biology. Biomolecules , 923-942.
15. Muzarelli, R. A. (1997). Human Enzymatic Activities Related to the Therapeutic Administration of Chitin Derivatives. Cell Mol Life Science, 131-140.
16. Qian-ying Deng, C.-r. Z.-h. (2006). Preparation and Characterization of Chitosan Nanoparticles Containing Lysozyme. Pharmaceutical Biology, 336-342.
17. R, K. (2012). Textile Dying Industry An Environmantal Hazard. Nature Science, 5.
18. Rita, K. (2012). Textile Dying Industry An Environmantal Hazard. Nature Science , 5-10.
19. Rinaudo, M. (2006). Chitin and Chitiosan Properties and Applications. Progress in Polymer Science, 603-632.
20. S, R. D. (2017). Textile Organic dyes:Polluting effects and elimination methods from textile waste water. International Journal of Chemical Engineering Research, 121-136.
21. Saini, D. R. (2018). Synthetic Textile Dyes: Constitution, Dying process and Environmental Impacts. Research Chem , 206-214.
22. Sharma, S., & Bhattacharya, A. (2016). Drinking water contamination and treatment techniques. Applied Water Science , 1043–1067.
23. S.SenthilkumaaraP.KalaamanibK.PorkodiaP.R.VaradarajancC.V.Subburaamd. (2006). Adsorption of dissolved Reactive red dye from aqueous phase onto activated carbon prepared from agricultural waste. Bioresource Technology, 1618-1625.
24. T.López-LeónaE.L.S.CarvalhobB.SeijobJ.L.Ortega-VinuesaaD.Bastos-Gonzáleza. (2005). Physicochemical characterization of chitosan nanoparticles: electrokinetic and stability behavior. Journal of Colloid and Interface Science, 344-351.
25. Tsugita, A. (1990). Database Activity in Japan. Japan: Nature.
26. Zanoni, P. A. (2005). Evaluation of different electrochemical methods on the oxidation and degradation of Reactive Blue 4 in aqueous solution. Chemosphere, 431-439.
